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  • Cu2+ Ions with Ammonia (NH3)
  • [Cu(H20)6]2+
  • Cu(OH)2 precipitate
  • [Cu(NH3)4(H20)2]2+
  • Cu2+ Ions with Hydrochloric Acid (HCl)
  • [Cu(H20)6]2+
  • [CuCl4]2-
  • [CuCl4]2- with water
  • Cr3+ Ions with Ammonia (NH3)
  • [Cr(H20)6]3+
  • Cr(OH)3 precipitate
  • [Cr(NH3)6]3+
  • When Copper(II) Sulphate is dissolved in water, the pale blue complex ion, [Cu(H20)6]2+ is formed in aqueous solution.When ammonia is added drop-wise to this solution a pale blue precipitate of Cu(OH)2 is formed.When ammonia is then added in excess a dark-blue solution of [Cu(NH3)4(H20)2]2+
  • Cu2+, Fe2+, Fe3+ and Mn2+ with NaOH(aq)
  • Cu2+
  • Fe(OH)2(s)
  • Cu(OH)2(s)
  • When Copper(II) Sulphate is dissolved in water, the pale blue complex ion, [Cu(H20)6]2+ is formed in aqueous solution.When an excess of hydrochloric acid to this solution a yellow solution of [CuCl4]2- is formed.If water is added to this yellow solution it turns pale blue but paler and more dilute than the original blue solution.
  • Cr3+ Ions with NaOH
  • When chromium(III) Potassium sulphate is dissolved in water, the pale purple / violet solution [Cr(H20)6]3+ is formed.When ammonia is added dropwise to this solution a grey-green precipitate of Cr(OH)3 is formed. When excess ammonia is added a purple solution of [Cr(NH3)6]3+ is formed.
  • Redox Reactions of Fe, Cr and Cu
  • MnO4-
  • Acidic Conditions
  • Mn2+
  • I- Ions react with Fe3+
  • Iron (Fe)
  • Fe3+
  • Brown I2 colour obscure pale green colour
  • Fe2+
  • Blue CU2+ reacts with NaOH to produce a blue precipitate of Cu(OH)2Pale green Fe2+ reacts with NaOH / NH3 to produce a green precipitate of Fe(OH)2. This can then react with air to be oxidised into an orange-brown precipitate of Fe(OH)3.Yellow Fe3+ reacts with NaOH / NH3 to produce an orange-brown precipitate of Fe(OH)3.Pale pink Mn2+ reacts with NaOH / NH3 to produce a light brown precipitate of Mn(OH)2.
  • Fe2+
  • Mn2+
  • Fe3+
  • Mn(OH)2
  • Fe(OH)3(s)
  • When a violet solution of Cr3+ ions reacts with NaOH to form a grey-green precipitate of chromium(II) hydroxide. When an excess of NaOH is added the precipitate dissolves to form a dark green solution of [Cr(OH)6]3-.
  • Cr3+
  • Cr(OH)3Precipitate
  • [Cr(OH)6]3-
  • When Fe2+ is added to purple MnO4- in acidic conditions it is reduced to colourless Mn2+. When orange-brown Fe3+ reacts with I- ions it is reduced to pale-green Fe2+.When orange Cr2O72- ions are added to Zn it is reduced to green Cr3+, when the Zn is in excess a pale blue Cr2+ is formed. When green Cr3+ is added to H2O2 it is oxidised to orange Cr2O72-. When pale blue Cu2+ ions react with I- it is reduced to a white precipitate of CuI. When Cu2O is added to H2SO4 it is reduced to a brown precipitate of Cu and oxidised to a blue CuSO4.
  • Cu2+
  • Cr2O72-
  • Cr3+
  • Cu+
  • White precipitate of CuI
  • Cr2+
  • Cupper(Cu)
  • Chromium(Cr)
  • Zn is added in excess
  • Cu2O + H2SO4
  • Cr3+
  • H2O2 Oxy Agent
  • Brown Copper precipitate
  • Cr2O72-
  • CuSO4
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